Information card for entry 7104100

Structure parameters

• Formula: C40 H96 Cl2 In3 Rh Si9
• Calculated formula: C40 H96 Cl2 In3 Rh Si9
• SMILES: [Cl]1[In]2([Cl][In]([Rh]34562([c]2([c]3([c]6([c]5([c]42C)C)C)C)C)[In]1C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal‒group 13 metal bond formation
• Authors of publication: Steinke, Tobias; Gemel, Christian; Cokoja, Mirza; Winter, Manuela; Fischer, Roland A.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 9
• Pages of publication: 1066 - 1067
• a: 14.509 ± 0.003 Å
• b: 18.83 ± 0.004 Å
• c: 22.633 ± 0.004 Å
• α: 90°
• β: 92.882 ± 0.004°
• γ: 90°
• Cell volume: 6176 ± 2 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0617
• Residual factor for significantly intense reflections: 0.0417
• Weighted residual factors for significantly intense reflections: 0.0943
• Weighted residual factors for all reflections included in the refinement: 0.1039
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No