Information card for entry 7104099

Structure parameters

• Common name: [(Ph2PCH2CH2PPH2)Pt{tBuCH2PH(O)C(SiMe3)2}]
• Formula: C52 H82 O4.5 P4 Pt Si2
• Calculated formula: C55.5 H54 O P4 Pt Si2
• Title of publication: Synthesis of a η2-2,3-diphosphabutadiene complex of zerovalent platinum from the corresponding η2-phosphaalkyne complex
• Authors of publication: Araujo, Maria Helena; Hitchcock, Peter B.; Nixon, John F.; Kuehner, Uwe; Stelzer, Othmar
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 9
• Pages of publication: 1092 - 1093
• a: 27.187 ± 0.005 Å
• b: 19.897 ± 0.008 Å
• c: 20.892 ± 0.006 Å
• α: 90°
• β: 92.94 ± 0.02°
• γ: 90°
• Cell volume: 11286.4 ± 6 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0913
• Residual factor for significantly intense reflections: 0.0609
• Weighted residual factors for all reflections: 0.1681
• Weighted residual factors for significantly intense reflections: 0.1468
• Goodness-of-fit parameter for all reflections: 1.059
• Goodness-of-fit parameter for significantly intense reflections: 1.104
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No