Information card for entry 7107825

Structure parameters

• Formula: C18 H26 N O5 P S Si2 W
• Calculated formula: C18 H26 N O5 P S Si2 W
• SMILES: [C@H]12C(=CN(C)[P@@]1(C([Si](C)(C)C)[Si](C)(C)C)[W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])C=CS2.[C@@H]12C(=CN(C)[P@]1(C([Si](C)(C)C)[Si](C)(C)C)[W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])C=CS2
• Title of publication: The difference between the reactivity of a terminal phosphinidene and a Li/Cl phosphiniodenoid complex in cycloaddition chemistry ‒ in the importance of template-induced selectivity
• Authors of publication: Rainer Streubel; Jose Manuel Villalba Franco; Gregor Schnakenburg; Arturo Espinosa Ferao
• Journal of publication: Chem.Commun.
• Year of publication: 2012
• Journal volume: 48
• Pages of publication: 5986
• a: 8.7938 ± 0.0003 Å
• b: 10.6257 ± 0.0004 Å
• c: 14.0699 ± 0.0005 Å
• α: 107.332 ± 0.001°
• β: 94.398 ± 0.001°
• γ: 96.224 ± 0.001°
• Cell volume: 1239.35 ± 0.08 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0177
• Residual factor for significantly intense reflections: 0.0167
• Weighted residual factors for significantly intense reflections: 0.0386
• Weighted residual factors for all reflections included in the refinement: 0.0391
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No