Information card for entry 7108651

Structure parameters

• Formula: C38 H66 Li4 N6 Si4
• Calculated formula: C38 H66 Li4 N6 Si4
• SMILES: [Li]1[N](=Cc2c3c(n([Li][N]([Li][N](=Cc4c5c(n([Li][N]1([Si](C)(C)C)[Si](C)(C)C)c4)cccc5)C(C)(C)C)([Si](C)(C)C)[Si](C)(C)C)c2)cccc3)C(C)(C)C
• Title of publication: Rare-earth metal complexes having an unusual indolyl-1,2-dianion through C–H activation with a novel η1:(μ2–η1:η1) bonding with metals
• Authors of publication: Zhu, Xiancui; Zhou, Shuangliu; Wang, Shaowu; Wei, Yun; Zhang, Lijun; Wang, Fenhua; Wang, Shaoyin; Feng, Zhijun
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2012
• Journal volume: 48
• Journal issue: 98
• Pages of publication: 12020 - 12022
• a: 9.1116 ± 0.0008 Å
• b: 11.2374 ± 0.001 Å
• c: 12.0801 ± 0.0011 Å
• α: 97.257 ± 0.001°
• β: 100.059 ± 0.001°
• γ: 101.907 ± 0.001°
• Cell volume: 1174.63 ± 0.18 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0617
• Residual factor for significantly intense reflections: 0.0434
• Weighted residual factors for significantly intense reflections: 0.1204
• Weighted residual factors for all reflections included in the refinement: 0.134
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No