Information card for entry 7108706

Structure parameters

• Formula: C32 H112 Ce5 Cl7 N8 Si16
• Calculated formula: C32 H112 Ce5 Cl7 N8 Si16
• SMILES: C[SiH](C)N([Ce]123([Cl]4[Ce]567(N([SiH](C)C)[SiH](C)C)[N]8([SiH](C)(C)[Ce]9%1048([Cl]45[Ce]5(N([SiH](C)C)[SiH](C)C)([Cl]26)([Cl]7)[N]([Ce]4(N([SiH](C)C)[SiH](C)C)([Cl]35)([Cl]19)[Cl]%10)([SiH](C)C)[SiH](C)C)N([SiH](C)C)[SiH](C)C)[SiH](C)C)N([SiH](C)C)[SiH](C)C)[SiH](C)C
• Title of publication: A homoleptic tetravalent cerium silylamide
• Authors of publication: Alan R. Crozier; Andre M. Bienfait; Cacilia Maichle-Mossmer; Karl W. Tornroos; Reiner Anwander
• Journal of publication: Chem.Commun.
• Year of publication: 2013
• Journal volume: 49
• Pages of publication: 87
• a: 17.281 ± 0.0006 Å
• b: 25.5225 ± 0.0009 Å
• c: 19.8095 ± 0.0007 Å
• α: 90°
• β: 100.203 ± 0.0004°
• γ: 90°
• Cell volume: 8598.9 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0241
• Residual factor for significantly intense reflections: 0.021
• Weighted residual factors for significantly intense reflections: 0.0532
• Weighted residual factors for all reflections included in the refinement: 0.0549
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No