Information card for entry 7109978

Structure parameters

• Formula: C34 H34 N P Si
• Calculated formula: C34 H34 N P Si
• SMILES: [SiH](c1ccccc1P(=NC(C)(C)C)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine
• Authors of publication: Kano, Naokazu; Yanaizumi, Kazuhide; Meng, Xiangtai; Havare, Nizam; Kawashima, Takayuki
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2013
• Journal volume: 49
• Journal issue: 88
• Pages of publication: 10373 - 10375
• a: 17.002 ± 0.009 Å
• b: 8.839 ± 0.005 Å
• c: 20.361 ± 0.012 Å
• α: 90°
• β: 112.614 ± 0.0019°
• γ: 90°
• Cell volume: 2825 ± 3 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 5
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0529
• Residual factor for significantly intense reflections: 0.0402
• Weighted residual factors for significantly intense reflections: 0.0354
• Weighted residual factors for all reflections included in the refinement: 0.039
• Goodness-of-fit parameter for all reflections included in the refinement: 0.79
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No