Information card for entry 7109979

Structure parameters

• Formula: C25 H32 N P Si
• Calculated formula: C25 H32 N P Si
• SMILES: [Si](c1ccccc1P(c1ccccc1)(c1ccccc1)=NC(C)(C)C)(C)(C)C
• Title of publication: Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine
• Authors of publication: Kano, Naokazu; Yanaizumi, Kazuhide; Meng, Xiangtai; Havare, Nizam; Kawashima, Takayuki
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2013
• Journal volume: 49
• Journal issue: 88
• Pages of publication: 10373 - 10375
• a: 8.745 ± 0.002 Å
• b: 16.531 ± 0.004 Å
• c: 16.017 ± 0.004 Å
• α: 90°
• β: 97.8059 ± 0.0011°
• γ: 90°
• Cell volume: 2294 ± 1 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0363
• Residual factor for significantly intense reflections: 0.0335
• Weighted residual factors for significantly intense reflections: 0.0908
• Weighted residual factors for all reflections included in the refinement: 0.0928
• Goodness-of-fit parameter for all reflections included in the refinement: 1.076
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No