Information card for entry 7110497

Structure parameters

• Formula: C48 H50 Cl4 N2 O4 Os P2 S2 Sn
• Calculated formula: C48 H50 Cl4 N2 O4 Os P2 S2 Sn
• Title of publication: The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2: structural comparisons with the analogous silatrane complex Os(Si[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2
• Authors of publication: Rickard, Clifton E. F.; Roper, Warren R.; Woodman, Timothy J.; James Wright, L.
• Journal of publication: Chemical Communications
• Year of publication: 1999
• Journal issue: 9
• Pages of publication: 837
• a: 12.4567 ± 0.0001 Å
• b: 19.2826 ± 0.0002 Å
• c: 21.7933 ± 0.0002 Å
• α: 90°
• β: 100.76 ± 0.01°
• γ: 90°
• Cell volume: 5142.66 ± 0.19 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0409
• Residual factor for significantly intense reflections: 0.0354
• Weighted residual factors for significantly intense reflections: 0.0982
• Weighted residual factors for all reflections included in the refinement: 0.1022
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No