Information card for entry 7110557

Structure parameters

• Formula: C46 H46 Cl3 N O Os P2 Sn
• Calculated formula: C46 H46 Cl3 N O Os P2 Sn
• SMILES: [Os]([Sn](Cl)(C)C)([P](c1ccccc1)(c1ccccc1)c1ccccc1)([P](c1ccccc1)(c1ccccc1)c1ccccc1)([n]1ccccc1)(C)C#[O].C(Cl)Cl
• Title of publication: Reversible methyl group migration between osmium and tin in reactions of osmium trimethylstannyl complexes
• Authors of publication: Rickard, Clifton E. F.; Roper, Warren R.; Woodman, Timothy J.; James Wright, L.
• Journal of publication: Chemical Communications
• Year of publication: 1999
• Journal issue: 12
• Pages of publication: 1101
• a: 9.6249 ± 0.0001 Å
• b: 12.551 ± 0.0002 Å
• c: 19.6568 ± 0.0003 Å
• α: 96.708 ± 0.001°
• β: 97.968 ± 0.001°
• γ: 107.02 ± 0.01°
• Cell volume: 2217.39 ± 0.14 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0396
• Residual factor for significantly intense reflections: 0.0384
• Weighted residual factors for significantly intense reflections: 0.0944
• Weighted residual factors for all reflections included in the refinement: 0.0954
• Goodness-of-fit parameter for all reflections included in the refinement: 1.066
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No