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Information card for entry 7111305
Preview
Coordinates | 7111305.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C19 H26 Br O5 P Si2 W |
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Calculated formula | C19 H26 Br O5 P Si2 W |
SMILES | [W]([P](Br)(C([Si](C)(C)C)[Si](C)(C)C)Cc1ccccc1)(C#[O])(C#[O])(C#[O])(C#[O])C#[O] |
Title of publication | Electrophilic terminal phosphinidene complex?Lewis base adducts: Chemistry between carbon?halide bond activation and weak Lewis base adduct formation |
Authors of publication | Ali Khan, Arif; Wismach, Cathleen; Jones, Peter G.; Streubel, Rainer |
Journal of publication | Chemical Communications |
Year of publication | 2003 |
Journal issue | 23 |
Pages of publication | 2892 |
a | 9.0099 ± 0.0006 Å |
b | 10.2351 ± 0.0006 Å |
c | 14.4398 ± 0.0011 Å |
α | 87.965 ± 0.004° |
β | 88.558 ± 0.004° |
γ | 68.778 ± 0.004° |
Cell volume | 1240.4 ± 0.15 Å3 |
Cell temperature | 133 ± 2 K |
Ambient diffraction temperature | 133 ± 2 K |
Number of distinct elements | 7 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0299 |
Residual factor for significantly intense reflections | 0.0231 |
Weighted residual factors for significantly intense reflections | 0.0486 |
Weighted residual factors for all reflections included in the refinement | 0.0502 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.002 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/7111305.html
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