Information card for entry 7111306

Structure parameters

• Formula: C12 H20 Br O5 P Si2 W
• Calculated formula: C12 H20 Br O5 P Si2 W
• SMILES: [W]([PH](Br)C([Si](C)(C)C)[Si](C)(C)C)(C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Electrophilic terminal phosphinidene complex?Lewis base adducts: Chemistry between carbon?halide bond activation and weak Lewis base adduct formation
• Authors of publication: Ali Khan, Arif; Wismach, Cathleen; Jones, Peter G.; Streubel, Rainer
• Journal of publication: Chemical Communications
• Year of publication: 2003
• Journal issue: 23
• Pages of publication: 2892
• a: 6.9656 ± 0.0002 Å
• b: 9.4476 ± 0.0003 Å
• c: 16.075 ± 0.0005 Å
• α: 74.99 ± 0.001°
• β: 88.901 ± 0.001°
• γ: 82.853 ± 0.001°
• Cell volume: 1013.74 ± 0.05 ų
• Cell temperature: 133 ± 2 K
• Ambient diffraction temperature: 133 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0204
• Residual factor for significantly intense reflections: 0.0192
• Weighted residual factors for significantly intense reflections: 0.0506
• Weighted residual factors for all reflections included in the refinement: 0.051
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No