Information card for entry 7111363

Structure parameters

• Formula: C36 H13 F16 P Pt S3
• Calculated formula: C36 H13 F16 P Pt S3
• SMILES: [Pt]1([P](c2c([S]1c1c(F)c(F)cc(F)c1F)c(c(c(c2F)F)F)F)(c1ccccc1)c1ccccc1)(Sc1c(F)c(F)cc(F)c1F)Sc1c(F)c(F)cc(F)c1F
• Title of publication: Conversion of [Pt(SRf)2(PPh2 ? n(C6F5)n + 1)2] ( n = 0 or 1, Rf?C6HF4-4) through carbon?fluorine bond activation to [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]Electronic Supplementary Information (ESI) available: experimental procedures and spectral data for all new compounds and crystallographic data for 5, 8 and 10. http://www.rsc.org/suppdata/cc/b4/b407328b/
• Authors of publication: Villanueva, Luis; Arroyo, Maribel; Bern�s, Sylvain; Torrens, Hugo
• Journal of publication: Chemical Communications
• Year of publication: 2004
• Journal issue: 17
• Pages of publication: 1942 - 1943
• a: 11.945 ± 0.003 Å
• b: 12.0754 ± 0.0014 Å
• c: 13.4898 ± 0.0018 Å
• α: 102.108 ± 0.01°
• β: 102.397 ± 0.017°
• γ: 105.499 ± 0.014°
• Cell volume: 1756 ± 0.6 ų
• Cell temperature: 293 ± 1 K
• Ambient diffraction temperature: 293 ± 1 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0713
• Residual factor for significantly intense reflections: 0.0431
• Weighted residual factors for significantly intense reflections: 0.0807
• Weighted residual factors for all reflections included in the refinement: 0.1023
• Goodness-of-fit parameter for all reflections included in the refinement: 1.167
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No