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Information card for entry 7111364
Preview
Coordinates | 7111364.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C36 H8 F21 P Pt S3 |
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Calculated formula | C36 H8 F21 P Pt S3 |
SMILES | [Pt]1([P](c2c([S]1c1c(c(cc(c1F)F)F)F)c(c(c(c2F)F)F)F)(c1ccccc1)c1c(c(c(c(c1F)F)F)F)F)(Sc1c(c(cc(c1F)F)F)F)Sc1c(c(cc(c1F)F)F)F |
Title of publication | Conversion of [Pt(SRf)2(PPh2 ? n(C6F5)n + 1)2] ( n = 0 or 1, Rf?C6HF4-4) through carbon?fluorine bond activation to [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]Electronic Supplementary Information (ESI) available: experimental procedures and spectral data for all new compounds and crystallographic data for 5, 8 and 10. http://www.rsc.org/suppdata/cc/b4/b407328b/ |
Authors of publication | Villanueva, Luis; Arroyo, Maribel; Bern�s, Sylvain; Torrens, Hugo |
Journal of publication | Chemical Communications |
Year of publication | 2004 |
Journal issue | 17 |
Pages of publication | 1942 - 1943 |
a | 11.8338 ± 0.001 Å |
b | 12.4575 ± 0.0014 Å |
c | 14.5848 ± 0.0013 Å |
α | 96.898 ± 0.008° |
β | 107.898 ± 0.007° |
γ | 105.595 ± 0.007° |
Cell volume | 1921.9 ± 0.4 Å3 |
Cell temperature | 296 ± 1 K |
Ambient diffraction temperature | 296 ± 1 K |
Number of distinct elements | 6 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.046 |
Residual factor for significantly intense reflections | 0.0348 |
Weighted residual factors for significantly intense reflections | 0.0798 |
Weighted residual factors for all reflections included in the refinement | 0.0849 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.042 |
Diffraction radiation probe | x-ray |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7111364.html
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