Information card for entry 7113816

Structure parameters

• Formula: C176 H136 Ag6 F12 N8 O12 P10 Re4
• Calculated formula: C176 H136 Ag6 F12 N8 O12 P10 Re4
• SMILES: [Ag]123[P](c4ccccc4)(c4ccccc4)C[P](c4ccccc4)(c4ccccc4)[Ag]4[C]1(=C=C=C=[Re]1(C#[O])(C#[O])(C#[O])[n]5ccc(cc5c5[n]1ccc(c5)C)C)[Ag]1[C]5(=C=C=C=[Re]6(C#[O])(C#[O])(C#[O])[n]7ccc(cc7c7[n]6ccc(c7)C)C)[Ag]([C]2(=C=C=C=[Re]2(C#[O])(C#[O])(C#[O])[n]6ccc(cc6c6[n]2ccc(c6)C)C)[Ag]2[P](c6ccccc6)(c6ccccc6)C[P](c6ccccc6)(c6ccccc6)[Ag]5([P](c5ccccc5)(c5ccccc5)C[P]1(c1ccccc1)c1ccccc1)[C]42=C=C=C=[Re]1(C#[O])(C#[O])(C#[O])[n]2ccc(cc2c2[n]1ccc(c2)C)C)[P](c1ccccc1)(c1ccccc1)C[P]3(c1ccccc1)c1ccccc1.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Synthesis and luminescence behaviour of novel heterodecanuclear silver(i)?rhenium(i) alkynyl complexes. X-Ray crystal structures of [Ag6(�-dppm)4{�3-C?CC?C?Re(Me2bpy)(CO)3}4](PF6)2 and [Ag6(�-dppm)4{�3-C?CC?C?Re(Br2phen)(CO)3}4](PF6)2Electronic supplementary information (ESI) available: characterisation for 1?4, perspective drawing of the complex cation of 4, and detailed X-ray crystal structure determination data for 2 and 4. See http://www.rsc.org/suppdata/cc/b3/b307479j/
• Authors of publication: Yam, Vivian Wing-Wah; Lo, Wing-Yin; Zhu, Nianyong
• Journal of publication: Chemical Communications
• Year of publication: 2003
• Journal issue: 19
• Pages of publication: 2446
• a: 20.082 ± 0.004 Å
• b: 29.961 ± 0.006 Å
• c: 35.827 ± 0.007 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 21556 ± 7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.1131
• Residual factor for significantly intense reflections: 0.0683
• Weighted residual factors for significantly intense reflections: 0.1819
• Weighted residual factors for all reflections included in the refinement: 0.2123
• Goodness-of-fit parameter for all reflections included in the refinement: 0.996
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No