Information card for entry 7118682

Structure parameters

• Formula: C40 H52 Au Cl3 N3 P Si
• Calculated formula: C40 H52 Au Cl3 N3 P Si
• SMILES: C1(c2ccccc2)=[N](C(C)(C)C)[Si]([Au]Cl)(N(c2c(C(C)C)cccc2C(C)C)P(c2ccccc2)c2ccccc2)N1C(C)(C)C.C(Cl)Cl
• Title of publication: Stepwise isolation of an unprecedented silylene supported dinuclear gold(i) cation with aurophilic interaction.
• Authors of publication: Khan, Shabana; Pal, Shiv; Kathewad, Neha; Purushothaman, Indu; De, Susmita; Parameswaran, Pattiyil
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2016
• Journal volume: 52
• Journal issue: 20
• Pages of publication: 3880 - 3882
• a: 11.933 ± 0.011 Å
• b: 12.334 ± 0.013 Å
• c: 17.499 ± 0.016 Å
• α: 81.27 ± 0.03°
• β: 82.82 ± 0.02°
• γ: 65.87 ± 0.02°
• Cell volume: 2318 ± 4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0982
• Residual factor for significantly intense reflections: 0.0752
• Weighted residual factors for significantly intense reflections: 0.2087
• Weighted residual factors for all reflections included in the refinement: 0.2296
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No