Information card for entry 7118683

Structure parameters

• Formula: C80 H104 Au2 Cl4 F12 N6 P2 Sb2 Si2
• Calculated formula: C80 H104 Au2 Cl4 F12 N6 P2 Sb2 Si2
• SMILES: c1(cccc(c1N1[P](c2ccccc2)(c2ccccc2)[Au]2[Au]([Si]31[N](C(C)(C)C)=C(N3C(C)(C)C)c1ccccc1)[P](c1ccccc1)(N(c1c(cccc1C(C)C)C(C)C)[Si]12[N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)c1ccccc1)C(C)C)C(C)C.F[Sb](F)(F)(F)(F)[F-].C(Cl)Cl.F[Sb](F)(F)(F)(F)[F-].C(Cl)Cl
• Title of publication: Stepwise isolation of an unprecedented silylene supported dinuclear gold(i) cation with aurophilic interaction.
• Authors of publication: Khan, Shabana; Pal, Shiv; Kathewad, Neha; Purushothaman, Indu; De, Susmita; Parameswaran, Pattiyil
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2016
• Journal volume: 52
• Journal issue: 20
• Pages of publication: 3880 - 3882
• a: 12.058 ± 0.006 Å
• b: 14.762 ± 0.009 Å
• c: 15.001 ± 0.009 Å
• α: 116.997 ± 0.014°
• β: 104.713 ± 0.014°
• γ: 95.716 ± 0.014°
• Cell volume: 2229 ± 2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0985
• Residual factor for significantly intense reflections: 0.0571
• Weighted residual factors for significantly intense reflections: 0.1046
• Weighted residual factors for all reflections included in the refinement: 0.121
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No