Information card for entry 7121067

Structure parameters

• Formula: C24 H18 F10 N Rh
• Calculated formula: C24 H18 F10 N Rh
• SMILES: [Rh]1234([N]#CC)([c]5([c]4([c]2([c]1([c]35C)C)C)C)C)(c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: Hidden aryl-exchange processes in stable 16e Rh^III [RhCp*Ar₂] complexes, and their unexpected transmetalation mechanism.
• Authors of publication: Peñas-Defrutos, M N; Bartolomé, C; García-Melchor, M; Espinet, P.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 8
• Pages of publication: 984 - 987
• a: 8.8736 ± 0.0004 Å
• b: 9.2267 ± 0.0003 Å
• c: 16.5011 ± 0.0007 Å
• α: 85.672 ± 0.004°
• β: 75.218 ± 0.004°
• γ: 61.708 ± 0.004°
• Cell volume: 1148.61 ± 0.09 ų
• Cell temperature: 294 K
• Ambient diffraction temperature: 294 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0337
• Residual factor for significantly intense reflections: 0.0309
• Weighted residual factors for significantly intense reflections: 0.078
• Weighted residual factors for all reflections included in the refinement: 0.0805
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No