Information card for entry 7121069

Structure parameters

• Formula: C32 H32 F10 O2 Rh2
• Calculated formula: C32 H32 F10 O2 Rh2
• SMILES: [Rh]12345([OH][Rh]6789([OH]1)(c1c(F)c(F)c(F)c(F)c1F)[c]1([c]6([c]8([c]9([c]71C)C)C)C)C)([c]1([c]2([c]3([c]5([c]41C)C)C)C)C)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: Hidden aryl-exchange processes in stable 16e Rh^III [RhCp*Ar₂] complexes, and their unexpected transmetalation mechanism.
• Authors of publication: Peñas-Defrutos, M N; Bartolomé, C; García-Melchor, M; Espinet, P.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 8
• Pages of publication: 984 - 987
• a: 10.8682 ± 0.0005 Å
• b: 16.2215 ± 0.0007 Å
• c: 18.4548 ± 0.0008 Å
• α: 90°
• β: 92.287 ± 0.004°
• γ: 90°
• Cell volume: 3251 ± 0.2 ų
• Cell temperature: 294 K
• Ambient diffraction temperature: 294 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0663
• Residual factor for significantly intense reflections: 0.0391
• Weighted residual factors for significantly intense reflections: 0.0755
• Weighted residual factors for all reflections included in the refinement: 0.0901
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No