Unexpected behaviour in derivatives of Barluenga's reagent, Hal(Coll)<sub>2</sub>X (Coll = 2,4,6-trimethyl pyridine, collidine; Hal = I, Br; X = PF<sub>6</sub>, ClO<sub>4</sub> & BF<sub>4</sub>).
Authors of publication
Morgan, Lewis C. F.; Kim, Yejin; Blandy, Jack N.; Murray, Claire A.; Christensen, Kirsten E.; Thompson, Amber L.
Journal of publication
Chemical communications (Cambridge, England)
Year of publication
2018
Journal volume
54
Journal issue
70
Pages of publication
9849 - 9852
a
8.0754 ± 0.0002 Å
b
8.355 ± 0.0003 Å
c
15.6634 ± 0.0007 Å
α
99.537 ± 0.003°
β
98.842 ± 0.003°
γ
98.269 ± 0.003°
Cell volume
1014.16 ± 0.07 Å3
Cell temperature
300 K
Ambient diffraction temperature
300 K
Number of distinct elements
6
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0404
Residual factor for significantly intense reflections
0.0381
Weighted residual factors for all reflections
0.1042
Weighted residual factors for significantly intense reflections
0.1015
Weighted residual factors for all reflections included in the refinement
0.1042
Goodness-of-fit parameter for all reflections included in the refinement
