Unexpected behaviour in derivatives of Barluenga's reagent, Hal(Coll)<sub>2</sub>X (Coll = 2,4,6-trimethyl pyridine, collidine; Hal = I, Br; X = PF<sub>6</sub>, ClO<sub>4</sub> & BF<sub>4</sub>).
Authors of publication
Morgan, Lewis C. F.; Kim, Yejin; Blandy, Jack N.; Murray, Claire A.; Christensen, Kirsten E.; Thompson, Amber L.
Journal of publication
Chemical communications (Cambridge, England)
Year of publication
2018
Journal volume
54
Journal issue
70
Pages of publication
9849 - 9852
a
7.9723 ± 0.0002 Å
b
8.2018 ± 0.0003 Å
c
15.4695 ± 0.0005 Å
α
99.377 ± 0.003°
β
97.639 ± 0.002°
γ
100.448 ± 0.002°
Cell volume
967.59 ± 0.05 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
6
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.033
Residual factor for significantly intense reflections
0.0323
Weighted residual factors for all reflections
0.084
Weighted residual factors for significantly intense reflections
0.0836
Weighted residual factors for all reflections included in the refinement
0.084
Goodness-of-fit parameter for all reflections included in the refinement
