Information card for entry 7124215

Structure parameters

• Formula: C26 H31 Cl2 N2 Rh
• Calculated formula: C26 H30 Cl2 N2 Rh
• Title of publication: Modulation of Coordination Geometry of NCN and NCNC Rh Complexes for Ambidextrous Chiral Catalysts
• Authors of publication: Ito, Jun-ichi; Ishihara, Takahiro; Fukuoka, Takaki; Binti Mat Napi, Siti Rokiah; Kameo, Hajime; Nishiyama, Hisao
• Journal of publication: Chemical Communications
• Year of publication: 2019
• a: 16.4067 ± 0.001 Å
• b: 17.1103 ± 0.0011 Å
• c: 10.8096 ± 0.0007 Å
• α: 90°
• β: 127.088 ± 0.0014°
• γ: 90°
• Cell volume: 2420.7 ± 0.3 ų
• Cell temperature: 93 ± 0.2 K
• Ambient diffraction temperature: 93 ± 0.2 K
• Number of distinct elements: 5
• Space group number: 5
• Hermann-Mauguin space group symbol: C 1 2 1
• Hall space group symbol: C 2y
• Residual factor for all reflections: 0.0255
• Residual factor for significantly intense reflections: 0.0253
• Weighted residual factors for significantly intense reflections: 0.0761
• Weighted residual factors for all reflections included in the refinement: 0.0766
• Goodness-of-fit parameter for all reflections included in the refinement: 1.29
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No