Information card for entry 7124427

Structure parameters

• Formula: C23 H42 N O P2 Rh
• Calculated formula: C23 H42 N O P2 Rh
• Title of publication: Catalytic reduction of dinitrogen into tris(trimethylsilyl)amine using rhodium complexes with pyrrole-based PNP-type pincer ligand
• Authors of publication: Kawakami, Ryosuke; Kuriyama, Shogo; Tanaka, Hiromasa; Arashiba, Kazuya; Konomi, Asuka; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki
• Journal of publication: Chemical Communications
• Year of publication: 2019
• a: 15.2192 ± 0.0004 Å
• b: 13.0419 ± 0.0004 Å
• c: 14.5491 ± 0.0005 Å
• α: 90°
• β: 118.51 ± 0.008°
• γ: 90°
• Cell volume: 2537.6 ± 0.2 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0632
• Residual factor for significantly intense reflections: 0.0459
• Weighted residual factors for significantly intense reflections: 0.1035
• Weighted residual factors for all reflections included in the refinement: 0.1087
• Goodness-of-fit parameter for all reflections included in the refinement: 1.097
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No