Crystallography Open Database

Information card for entry 7124428

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Coordinates	7124428.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C42 H82 Cl K N O8 P2 Rh
Calculated formula	C42 H82 Cl K N O8 P2 Rh
Title of publication	Catalytic reduction of dinitrogen into tris(trimethylsilyl)amine using rhodium complexes with pyrrole-based PNP-type pincer ligand
Authors of publication	Kawakami, Ryosuke; Kuriyama, Shogo; Tanaka, Hiromasa; Arashiba, Kazuya; Konomi, Asuka; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki
Journal of publication	Chemical Communications
Year of publication	2019
a	30.3543 ± 0.0009 Å
b	10.6969 ± 0.0004 Å
c	31.0098 ± 0.001 Å
α	90°
β	92.302 ± 0.007°
γ	90°
Cell volume	10060.7 ± 0.6 Å³
Cell temperature	173 K
Ambient diffraction temperature	173 K
Number of distinct elements	8
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0605
Residual factor for significantly intense reflections	0.0374
Weighted residual factors for significantly intense reflections	0.0758
Weighted residual factors for all reflections included in the refinement	0.0837
Goodness-of-fit parameter for all reflections included in the refinement	0.99
Diffraction radiation wavelength	0.71075 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

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