Information card for entry 7124625

Structure parameters

• Common name: [Nb(BDI)(NPhtBu)(NB(C6F5)3)].(toluene)0.5
• Formula: C121 H118 B2 F30 N8 Nb2
• Calculated formula: C121 H118 B2 F30 N8 Nb2
• Title of publication: Photo-activation of d(0) niobium imido azides: en route to nitrido complexes.
• Authors of publication: Camp, Clément; Grant, Lauren N.; Bergman, Robert G.; Arnold, John
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2016
• Journal volume: 52
• Journal issue: 32
• Pages of publication: 5538 - 5541
• a: 19.3473 ± 0.0005 Å
• b: 22.4336 ± 0.0007 Å
• c: 25.5172 ± 0.0009 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 11075.2 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.053
• Residual factor for significantly intense reflections: 0.036
• Weighted residual factors for significantly intense reflections: 0.0801
• Weighted residual factors for all reflections included in the refinement: 0.0905
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No