Information card for entry 7124682

Structure parameters

• Formula: C66 H57 Ce F15 N3 O2 P2 S6 Si3
• Calculated formula: C66 H57 Ce F15 N3 O2 P2 S6 Si3
• Title of publication: Reactions of a cerium(iii) amide with heteroallenes: insertion, silyl-migration and de-insertion.
• Authors of publication: Yin, Haolin; Carroll, Patrick J.; Schelter, Eric J.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2016
• Journal volume: 52
• Journal issue: 63
• Pages of publication: 9813 - 9816
• a: 13.5981 ± 0.0006 Å
• b: 14.8764 ± 0.0007 Å
• c: 21.2531 ± 0.0009 Å
• α: 75.799 ± 0.002°
• β: 87.413 ± 0.002°
• γ: 75.372 ± 0.002°
• Cell volume: 4032.2 ± 0.3 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 ± 1 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0623
• Residual factor for significantly intense reflections: 0.0511
• Weighted residual factors for significantly intense reflections: 0.1185
• Weighted residual factors for all reflections included in the refinement: 0.1253
• Goodness-of-fit parameter for all reflections included in the refinement: 1.096
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No