Information card for entry 7124683

Structure parameters

• Formula: C48 H69 Ce F15 N9 Si3
• Calculated formula: C48 H69 Ce F15 N9 Si3
• Title of publication: Reactions of a cerium(iii) amide with heteroallenes: insertion, silyl-migration and de-insertion.
• Authors of publication: Yin, Haolin; Carroll, Patrick J.; Schelter, Eric J.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2016
• Journal volume: 52
• Journal issue: 63
• Pages of publication: 9813 - 9816
• a: 23.8 ± 0.0014 Å
• b: 12.7595 ± 0.0007 Å
• c: 40.727 ± 0.002 Å
• α: 90°
• β: 97.599 ± 0.003°
• γ: 90°
• Cell volume: 12259.2 ± 1.2 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 ± 1 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0535
• Residual factor for significantly intense reflections: 0.0499
• Weighted residual factors for significantly intense reflections: 0.1189
• Weighted residual factors for all reflections included in the refinement: 0.1204
• Goodness-of-fit parameter for all reflections included in the refinement: 1.166
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No