Total synthesis of dehaloperophoramidine using a highly diastereoselective Hosomi-Sakurai reaction.
Authors of publication
Wilkie, Ross P.; Neal, Andrew R.; Johnston, Craig A.; Voute, Nicholas; Lancefield, Christopher S.; Stell, Matthew D.; Medda, Federico; Makiyi, Edward F.; Turner, Emma M.; Stephen Ojo, O.; Slawin, Alexandra M. Z.; Lebl, Tomas; Mullen, Peter; Harrison, David J.; Ireland, Chris M.; Westwood, Nicholas J.
Journal of publication
Chemical communications (Cambridge, England)
Year of publication
2016
Journal volume
52
Journal issue
71
Pages of publication
10747 - 10750
a
6.691 ± 0.005 Å
b
29.96 ± 0.02 Å
c
12.952 ± 0.012 Å
α
90°
β
104.2 ± 0.02°
γ
90°
Cell volume
2517 ± 3 Å3
Cell temperature
173 K
Ambient diffraction temperature
173 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.2607
Residual factor for significantly intense reflections
0.1742
Weighted residual factors for significantly intense reflections
0.4114
Weighted residual factors for all reflections included in the refinement
0.4607
Goodness-of-fit parameter for all reflections included in the refinement
