Total synthesis of dehaloperophoramidine using a highly diastereoselective Hosomi-Sakurai reaction.
Authors of publication
Wilkie, Ross P.; Neal, Andrew R.; Johnston, Craig A.; Voute, Nicholas; Lancefield, Christopher S.; Stell, Matthew D.; Medda, Federico; Makiyi, Edward F.; Turner, Emma M.; Stephen Ojo, O.; Slawin, Alexandra M. Z.; Lebl, Tomas; Mullen, Peter; Harrison, David J.; Ireland, Chris M.; Westwood, Nicholas J.
Journal of publication
Chemical communications (Cambridge, England)
Year of publication
2016
Journal volume
52
Journal issue
71
Pages of publication
10747 - 10750
a
13.438 ± 0.003 Å
b
14.165 ± 0.002 Å
c
13.5796 ± 0.0019 Å
α
90°
β
93.657 ± 0.003°
γ
90°
Cell volume
2579.6 ± 0.8 Å3
Cell temperature
125 K
Ambient diffraction temperature
125 K
Number of distinct elements
5
Space group number
4
Hermann-Mauguin space group symbol
P 1 21 1
Hall space group symbol
P 2yb
Residual factor for all reflections
0.0607
Residual factor for significantly intense reflections
0.0594
Weighted residual factors for significantly intense reflections
0.1505
Weighted residual factors for all reflections included in the refinement
0.1522
Goodness-of-fit parameter for all reflections included in the refinement
