Information card for entry 7128207

Structure parameters

• Formula: C37 H54 Cl3 Li N4 P2 Si2 U
• Calculated formula: C37 H54 Cl3 Li N4 P2 Si2 U
• Title of publication: Fragmentation, catenation, and direct functionalisation of white phosphorus by a uranium(IV)-silyl-phosphino-carbene complex.
• Authors of publication: Boronski, Josef T.; Seed, John A.; Wooles, Ashley J.; Liddle, Stephen T.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2021
• Journal volume: 57
• Journal issue: 41
• Pages of publication: 5090 - 5093
• a: 12.67099 ± 0.00017 Å
• b: 21.463 ± 0.0002 Å
• c: 16.66143 ± 0.00017 Å
• α: 90°
• β: 93.0428 ± 0.0011°
• γ: 90°
• Cell volume: 4524.81 ± 0.09 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.047
• Residual factor for significantly intense reflections: 0.0453
• Weighted residual factors for significantly intense reflections: 0.1223
• Weighted residual factors for all reflections included in the refinement: 0.124
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No