Information card for entry 7130877

Structure parameters

• Formula: C32 H90 Cl2 Eu2 N6 Si10
• Calculated formula: C32 H90 Cl2 Eu2 N6 Si10
• Title of publication: Nitrile formation via dichlorocarbene insertion into the Si-N bond of Ln(III) bis(trimethylsilyl)amide complexes
• Authors of publication: Li, Yangjuan; Gong, Yu
• Journal of publication: Chemical Communications
• Year of publication: 2022
• a: 20.7513 ± 0.0004 Å
• b: 11.9059 ± 0.0002 Å
• c: 25.0124 ± 0.0004 Å
• α: 90°
• β: 93.4704 ± 0.0016°
• γ: 90°
• Cell volume: 6168.3 ± 0.19 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0229
• Residual factor for significantly intense reflections: 0.0187
• Weighted residual factors for significantly intense reflections: 0.0417
• Weighted residual factors for all reflections included in the refinement: 0.0429
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No