Crystallography Open Database

Information card for entry 7130879

Preview

Coordinates	7130879.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C32 H90 Cl2 N6 Si10 Sm2
Calculated formula	C32 H90 Cl2 N6 Si10 Sm2
Title of publication	Nitrile formation via dichlorocarbene insertion into the Si-N bond of Ln(III) bis(trimethylsilyl)amide complexes
Authors of publication	Li, Yangjuan; Gong, Yu
Journal of publication	Chemical Communications
Year of publication	2022
a	20.8019 ± 0.0003 Å
b	11.9155 ± 0.0002 Å
c	25.0378 ± 0.0004 Å
α	90°
β	93.368 ± 0.002°
γ	90°
Cell volume	6195.28 ± 0.17 Å³
Cell temperature	179.99 ± 0.1 K
Ambient diffraction temperature	179.99 ± 0.1 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0238
Residual factor for significantly intense reflections	0.0201
Weighted residual factors for significantly intense reflections	0.0435
Weighted residual factors for all reflections included in the refinement	0.0445
Goodness-of-fit parameter for all reflections included in the refinement	1.054
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7130879.html