Information card for entry 7131020

Structure parameters

• Formula: C9.11 H12.67 N1.11 Ni0.22 O0.11 Si0.22
• Calculated formula: C8.66667 H12.4444 N1.11111 Ni0.222222 Si0.222222
• Title of publication: Synthesis and reactivity of a -1,2-dinitrogen dinickel(II) complex with C-H activated silaamidinate pincer ligand
• Authors of publication: Hu , Chaopeng; Ding, Yazhou; Bai, Yunping; Guo, Lulu; Cui, Chunming
• Journal of publication: Chemical Communications
• Year of publication: 2022
• a: 15.2773 ± 0.0009 Å
• b: 16.5998 ± 0.0008 Å
• c: 18.2805 ± 0.001 Å
• α: 103.515 ± 0.005°
• β: 111.529 ± 0.005°
• γ: 96.493 ± 0.004°
• Cell volume: 4090.5 ± 0.4 ų
• Cell temperature: 113.15 K
• Ambient diffraction temperature: 113.15 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1312
• Residual factor for significantly intense reflections: 0.0682
• Weighted residual factors for significantly intense reflections: 0.1355
• Weighted residual factors for all reflections included in the refinement: 0.1615
• Goodness-of-fit parameter for all reflections included in the refinement: 1.005
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No