Information card for entry 7131046

Structure parameters

• Chemical name: C35H30AuBClF4PS
• Formula: C35 H30 Au B Cl F4 P S
• Calculated formula: C35 H30 Au B Cl F4 P S
• SMILES: [Au]1(Cl)([S]2CCCC2)[P](c2c(cccc2)C21c1c(cccc1)c1c2cccc1)(c1ccccc1)c1ccccc1.[B](F)(F)(F)[F-]
• Title of publication: A cationic gold-fluorenyl complex with a dative Au → C+ bond: synthesis, structure, and carbophilic reactivity
• Authors of publication: Litle, Elishua D.; Gabbaï, François P.
• Journal of publication: Chemical Communications
• Year of publication: 2023
• Journal volume: 59
• Journal issue: 5
• Pages of publication: 603 - 606
• a: 10.7567 ± 0.0005 Å
• b: 15.5643 ± 0.0008 Å
• c: 19.0588 ± 0.001 Å
• α: 90°
• β: 105.244 ± 0.002°
• γ: 90°
• Cell volume: 3078.6 ± 0.3 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0205
• Residual factor for significantly intense reflections: 0.018
• Weighted residual factors for significantly intense reflections: 0.0387
• Weighted residual factors for all reflections included in the refinement: 0.0396
• Goodness-of-fit parameter for all reflections included in the refinement: 1.086
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No