Information card for entry 7131047

Structure parameters

• Formula: C138 H86 Au2 B2 Cl2 F50 P2
• Calculated formula: C138 H86 Au2 B2 Cl2 F50 P2
• Title of publication: A cationic gold-fluorenyl complex with a dative Au → C+ bond: synthesis, structure, and carbophilic reactivity
• Authors of publication: Litle, Elishua D.; Gabbaï, François P.
• Journal of publication: Chemical Communications
• Year of publication: 2023
• Journal volume: 59
• Journal issue: 5
• Pages of publication: 603 - 606
• a: 12.836 ± 0.002 Å
• b: 17.581 ± 0.003 Å
• c: 17.82 ± 0.003 Å
• α: 63.266 ± 0.004°
• β: 89.509 ± 0.005°
• γ: 87.844 ± 0.004°
• Cell volume: 3588.9 ± 1 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1176
• Residual factor for significantly intense reflections: 0.0637
• Weighted residual factors for significantly intense reflections: 0.1642
• Weighted residual factors for all reflections included in the refinement: 0.1982
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No