Information card for entry 7133207

Structure parameters

• Common name: N-(10H-5λ^5^-5,10-[1,2]benzenoacridophosphin-5-ylidene)- 2,4,6-triisopropylbenzenesulfonamide
• Chemical name: N-(10H-5λ^5^-5,10-[1,2]benzenoacridophosphin-5-ylidene)- 2,4,6-triisopropylbenzenesulfonamide
• Formula: C34 H36 N O2 P S
• Calculated formula: C34 H36 N O2 P S
• Title of publication: Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines.
• Authors of publication: Hu, Lei; Chakraborty, Sayandip; Tumanov, Nikolay; Wouters, Johan; Robiette, Raphaël; Berionni, Guillaume
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• Journal volume: 60
• Journal issue: 55
• Pages of publication: 7073 - 7076
• a: 9.31097 ± 0.00012 Å
• b: 12.97197 ± 0.00017 Å
• c: 24.0692 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2907.12 ± 0.08 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0523
• Residual factor for significantly intense reflections: 0.0406
• Weighted residual factors for significantly intense reflections: 0.0901
• Weighted residual factors for all reflections included in the refinement: 0.0963
• Goodness-of-fit parameter for all reflections included in the refinement: 1.019
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No