Information card for entry 7133206

Structure parameters

• Common name: N-(10H-5l5-5,10-[1,2]benzenoacridophosphin-5-ylidene)-4- methylbenzenesulfonamide
• Chemical name: N-(10H-5l5-5,10-[1,2]benzenoacridophosphin-5-ylidene)-4- methylbenzenesulfonamide
• Formula: C26 H20 N O2 P S
• Calculated formula: C26 H20 N O2 P S
• Title of publication: Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines.
• Authors of publication: Hu, Lei; Chakraborty, Sayandip; Tumanov, Nikolay; Wouters, Johan; Robiette, Raphaël; Berionni, Guillaume
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• Journal volume: 60
• Journal issue: 55
• Pages of publication: 7073 - 7076
• a: 8.19512 ± 0.00014 Å
• b: 13.942 ± 0.0002 Å
• c: 19.4641 ± 0.0003 Å
• α: 90°
• β: 99.7093 ± 0.0016°
• γ: 90°
• Cell volume: 2192.04 ± 0.06 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.067
• Residual factor for significantly intense reflections: 0.0632
• Weighted residual factors for significantly intense reflections: 0.1784
• Weighted residual factors for all reflections included in the refinement: 0.1828
• Goodness-of-fit parameter for all reflections included in the refinement: 1.092
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No