Information card for entry 7133689

Structure parameters

• Formula: C51 H85 N3 O Si2 Sr
• Calculated formula: C51 H85 N3 O Si2 Sr
• Title of publication: A series of neutral alkaline earth metal hydride complexes supported by a bulky, unsymmetrical β-diketiminate ligand, [{(^Dip/TCHPNacnac)M(μ-H)}₂] (M = Mg, Ca, Sr or Ba).
• Authors of publication: Kennedy, Dominic B.; Evans, Matthew J.; Jones, Dafydd D. L.; Parr, Joseph M.; Hill, Michael S.; Jones, Cameron
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• Journal volume: 60
• Journal issue: 78
• Pages of publication: 10894 - 10897
• a: 12.68 ± 0.003 Å
• b: 18.66 ± 0.004 Å
• c: 22.47 ± 0.005 Å
• α: 90°
• β: 96.56 ± 0.03°
• γ: 90°
• Cell volume: 5282 ± 2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0525
• Residual factor for significantly intense reflections: 0.034
• Weighted residual factors for significantly intense reflections: 0.0819
• Weighted residual factors for all reflections included in the refinement: 0.089
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: Synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No