Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 7204350
Preview
Coordinates | 7204350.cif |
---|---|
Original paper (by DOI) | HTML |
External links | ChemSpider |
Formula | C27 H42 Sn |
---|---|
Calculated formula | C27 H42 Sn |
SMILES | [Sn]([C@@H]1[C@@]2(CC[C@H](C1)C2(C)C)C)([C@@H]1[C@@]2(CC[C@H](C1)C2(C)C)C)(c1ccccc1)C |
Title of publication | Synthesis of chiral organotin reagents: synthesis of enantiomerically enriched bicyclo[2.2.1]hept-2-yl tin hydrides from camphor. X-Ray crystal structures of (dimethyl)[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]tin chloride and methyl(phenyl)bis[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]stannane |
Authors of publication | Helliwell, Madeleine; Thomas, Eric J.; Townsend, Linda A. |
Journal of publication | Journal of the Chemical Society, Perkin Transactions 1 |
Year of publication | 2002 |
Journal issue | 10 |
Pages of publication | 1286 |
a | 10.072 ± 0.002 Å |
b | 25.978 ± 0.003 Å |
c | 9.617 ± 0.002 Å |
α | 90° |
β | 90° |
γ | 90° |
Cell volume | 2516.3 ± 0.8 Å3 |
Cell temperature | 296.2 K |
Ambient diffraction temperature | 296.2 K |
Number of distinct elements | 3 |
Space group number | 19 |
Hermann-Mauguin space group symbol | P 21 21 21 |
Hall space group symbol | P 2ac 2ab |
Residual factor for all reflections | 0.0472 |
Residual factor for significantly intense reflections | 0.0358 |
Weighted residual factors for all reflections | 0.0292 |
Weighted residual factors for significantly intense reflections | 0.0282 |
Goodness-of-fit parameter for all reflections | 2.086 |
Goodness-of-fit parameter for significantly intense reflections | 2.149 |
Diffraction radiation wavelength | 1.5418 Å |
Diffraction radiation type | CuKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7204350.html
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.