Information card for entry 7208682

Structure parameters

• Common name: (Ni(Ni(bpy)(H2O))8(W(CN)8)6). 11.8 H2O
• Chemical name: {Ni[Ni(bpy)(H2O)]8[W(CN)8]6}. 11.8 H2O
• Formula: C128 H103.6 N64 Ni9 O19.8 W6
• Calculated formula: C128 H64 N64 Ni9 O19.8 W6
• Title of publication: Geometrical isomerism in pentadecanuclear high-spin Ni9W6 clusters with symmetrical bidentate ligands detected
• Authors of publication: Nowicka, Beata; Stadnicka, Katarzyna; Nitek, Wojciech; Rams, Michał; Sieklucka, Barbara
• Journal of publication: CrystEngComm
• Year of publication: 2012
• Journal volume: 14
• Journal issue: 20
• Pages of publication: 6559
• a: 18.6069 ± 0.0011 Å
• b: 19.1286 ± 0.0009 Å
• c: 24.0604 ± 0.0014 Å
• α: 91.308 ± 0.002°
• β: 91.075 ± 0.003°
• γ: 94.282 ± 0.004°
• Cell volume: 8535.7 ± 0.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0803
• Residual factor for significantly intense reflections: 0.0471
• Weighted residual factors for significantly intense reflections: 0.1016
• Weighted residual factors for all reflections included in the refinement: 0.1144
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No