Information card for entry 7218176

Structure parameters

• Chemical name: [N-(4-pyridinyle)diphenylephosphinic amide-kappa-N chlorotriphenyltin(IV)]. N-(4-pyridinyle)diphenylephosphinic amide
• Formula: C52 H45 Cl N4 O2 P2 Sn
• Calculated formula: C52 H45 Cl N4 O2 P2 Sn
• SMILES: [Sn](Cl)([n]1ccc(NP(=O)(c2ccccc2)c2ccccc2)cc1)(c1ccccc1)(c1ccccc1)c1ccccc1.P(=O)(Nc1ccncc1)(c1ccccc1)c1ccccc1
• Title of publication: Steric and electronic control over the structural diversity of N-(n-pyridinyl) diphenylphosphinic amides (n = 2 and 4) as difunctional ligands in triphenyltin(iv) adducts
• Authors of publication: Gholivand, K.; Gholami, A.; Tizhoush, S. K.; Schenk, K. J.; Fadaei, F.; Bahrami, A.
• Journal of publication: RSC Adv.
• Year of publication: 2014
• Journal volume: 4
• Journal issue: 84
• Pages of publication: 44509
• a: 9.9181 ± 0.0006 Å
• b: 14.7686 ± 0.0009 Å
• c: 16.9564 ± 0.001 Å
• α: 82.955 ± 0.005°
• β: 81.181 ± 0.005°
• γ: 74.541 ± 0.005°
• Cell volume: 2356.8 ± 0.3 ų
• Cell temperature: 292 ± 2 K
• Ambient diffraction temperature: 292 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0699
• Residual factor for significantly intense reflections: 0.0491
• Weighted residual factors for significantly intense reflections: 0.1275
• Weighted residual factors for all reflections included in the refinement: 0.1557
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No