Information card for entry 7227273

Structure parameters

• Formula: C25 H44 N3 Si2 Y
• Calculated formula: C25 H44 N3 Si2 Y
• SMILES: [Y]123456([c]7([c]81cccc[c]28[cH]6[cH]47)CCN5[C@H]1[C@H]([N]3(C)C)CCCC1)N([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Half-Sandwich Chiral Rare-Earth Metal Complexes with Linked Tridentate Amido-Indenyl Ligand: Synthesis, Characterization, and Catalytic Properties for Intramolecular Hydroamination
• Authors of publication: Chai, Zhuo; Chu, Jiang; Qi, Yunyi; Tang, Mujun; Hou, Jinsong; Yang, Gaosheng
• Journal of publication: RSC Adv.
• Year of publication: 2016
• a: 8.955 ± 0.0014 Å
• b: 10.0767 ± 0.0016 Å
• c: 15.856 ± 0.002 Å
• α: 90°
• β: 98.022 ± 0.002°
• γ: 90°
• Cell volume: 1416.8 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.062
• Residual factor for significantly intense reflections: 0.0406
• Weighted residual factors for significantly intense reflections: 0.0861
• Weighted residual factors for all reflections included in the refinement: 0.0945
• Goodness-of-fit parameter for all reflections included in the refinement: 0.978
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No