Information card for entry 7227274

Structure parameters

• Formula: C25 H44 N3 Si2 Sm
• Calculated formula: C25 H44 N3 Si2 Sm
• SMILES: [Sm]123456(N([Si](C)(C)C)[Si](C)(C)C)N(CC[c]76[c]63cccc[c]46[cH]1[cH]57)[C@H]1[C@H]([N]2(C)C)CCCC1
• Title of publication: Half-Sandwich Chiral Rare-Earth Metal Complexes with Linked Tridentate Amido-Indenyl Ligand: Synthesis, Characterization, and Catalytic Properties for Intramolecular Hydroamination
• Authors of publication: Chai, Zhuo; Chu, Jiang; Qi, Yunyi; Tang, Mujun; Hou, Jinsong; Yang, Gaosheng
• Journal of publication: RSC Adv.
• Year of publication: 2016
• a: 8.9674 ± 0.0007 Å
• b: 10.0942 ± 0.0008 Å
• c: 16.0127 ± 0.0012 Å
• α: 90°
• β: 98.006 ± 0.001°
• γ: 90°
• Cell volume: 1435.32 ± 0.19 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0204
• Residual factor for significantly intense reflections: 0.0187
• Weighted residual factors for significantly intense reflections: 0.0443
• Weighted residual factors for all reflections included in the refinement: 0.0451
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No