Information card for entry 7238468

Structure parameters

• Common name: (Pd(PP3)2)Cl2.4CHCl3
• Chemical name: [Pd(PP3)2]Cl2.4CHCl3
• Formula: C88 H84 Cl14 P8 Pd
• Calculated formula: C88 H84 Cl14 P8 Pd
• Title of publication: Transition of trigonal-bipyramidal to square-planar geometries by oxidation of a coordinated tripodal polyphosphine in Pd(ii) and Pt(ii) complexes
• Authors of publication: Fernández-Anca, Damián; García-Seijo, M. Inés; García-Fernández, M. Esther
• Journal of publication: RSC Adv.
• Year of publication: 2012
• Journal volume: 2
• Journal issue: 4
• Pages of publication: 1404
• a: 14.942 ± 0.002 Å
• b: 18.073 ± 0.003 Å
• c: 17.298 ± 0.003 Å
• α: 90°
• β: 93.44 ± 0.004°
• γ: 90°
• Cell volume: 4662.9 ± 1.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1769
• Residual factor for significantly intense reflections: 0.0672
• Weighted residual factors for significantly intense reflections: 0.1506
• Weighted residual factors for all reflections included in the refinement: 0.1999
• Goodness-of-fit parameter for all reflections included in the refinement: 0.908
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No