Information card for entry 7238469

Structure parameters

• Common name: (Pd(P(PO)2)2)Cl2.2MeOH.6H2O
• Chemical name: [Pd(P(PO)2)2]Cl2.2MeOH.6H2O
• Formula: C86 H90 Cl2 O12 P8 Pd
• Calculated formula: C86 H90 Cl2 O12 P8 Pd
• Title of publication: Transition of trigonal-bipyramidal to square-planar geometries by oxidation of a coordinated tripodal polyphosphine in Pd(ii) and Pt(ii) complexes
• Authors of publication: Fernández-Anca, Damián; García-Seijo, M. Inés; García-Fernández, M. Esther
• Journal of publication: RSC Adv.
• Year of publication: 2012
• Journal volume: 2
• Journal issue: 4
• Pages of publication: 1404
• a: 11.808 ± 0.006 Å
• b: 13.975 ± 0.007 Å
• c: 15.675 ± 0.007 Å
• α: 105.495 ± 0.007°
• β: 98.909 ± 0.007°
• γ: 102.948 ± 0.007°
• Cell volume: 2365 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0998
• Residual factor for significantly intense reflections: 0.0685
• Weighted residual factors for significantly intense reflections: 0.2029
• Weighted residual factors for all reflections included in the refinement: 0.2402
• Goodness-of-fit parameter for all reflections included in the refinement: 1.095
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No