Information card for entry 7241900

Structure parameters

• Formula: C33 H23 O9 Os3 P2
• Calculated formula: C33 H23 O9 Os3 P2
• SMILES: [Os]1([P](c2ccccc2)(c2ccccc2)C[P]([Os](C#[O])(C#[O])O[OsH]1(C#[O])(C#[O])C#[O])(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O]
• Title of publication: A new synthetic route for the preparation of [Os3(CO)10(μ-OH)(μ-H)] and its reaction with bis(diphenylphosphino)methane (dppm): syntheses and X-ray structures of two isomers of [Os3(CO)8(μ-OH)(μ-H)(μ-dppm)] and [Os3(CO)7(μ3-CO)(μ3-O)(μ-dppm)]
• Authors of publication: Joy, Md. Tuhinur R.; Bhoumik, Nikhil C.; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.
• Journal of publication: RSC Advances
• Year of publication: 2020
• Journal volume: 10
• Journal issue: 73
• Pages of publication: 44699 - 44711
• a: 10.642 ± 0.007 Å
• b: 12.082 ± 0.009 Å
• c: 16.209 ± 0.013 Å
• α: 76.185 ± 0.019°
• β: 71.21 ± 0.03°
• γ: 73.02 ± 0.02°
• Cell volume: 1863 ± 2 ų
• Cell temperature: 193 ± 1 K
• Ambient diffraction temperature: 193 ± 1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0888
• Residual factor for significantly intense reflections: 0.0504
• Weighted residual factors for significantly intense reflections: 0.0909
• Weighted residual factors for all reflections included in the refinement: 0.1013
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No