Information card for entry 7241901

Structure parameters

• Formula: C36 H28 O11 Os3 P2
• Calculated formula: C36 H28 O11 Os3 P2
• SMILES: [Os]12([Os]([P](C[P]2(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)(C#[O])(C#[O])[O]=C([Os]1(C#[O])(C#[O])(C#[O])O)OCC)(C#[O])(C#[O])C#[O]
• Title of publication: A new synthetic route for the preparation of [Os3(CO)10(μ-OH)(μ-H)] and its reaction with bis(diphenylphosphino)methane (dppm): syntheses and X-ray structures of two isomers of [Os3(CO)8(μ-OH)(μ-H)(μ-dppm)] and [Os3(CO)7(μ3-CO)(μ3-O)(μ-dppm)]
• Authors of publication: Joy, Md. Tuhinur R.; Bhoumik, Nikhil C.; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.
• Journal of publication: RSC Advances
• Year of publication: 2020
• Journal volume: 10
• Journal issue: 73
• Pages of publication: 44699 - 44711
• a: 10.9749 ± 0.0008 Å
• b: 12.9394 ± 0.001 Å
• c: 14.3221 ± 0.0011 Å
• α: 74.898 ± 0.004°
• β: 89.703 ± 0.003°
• γ: 72.437 ± 0.003°
• Cell volume: 1866.1 ± 0.3 ų
• Cell temperature: 150 ± 1 K
• Ambient diffraction temperature: 150 ± 1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0221
• Residual factor for significantly intense reflections: 0.0176
• Weighted residual factors for significantly intense reflections: 0.0363
• Weighted residual factors for all reflections included in the refinement: 0.0377
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No