Information card for entry 7246160

Structure parameters

• Formula: C69 H52 O8 Os3 P2 Sb2
• Calculated formula: C69 H52 O8 Os3 P2 Sb2
• SMILES: [Os]12([Os]([Os]([Sb]1(c1ccccc1)c1ccccc1)([Sb](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])c1ccccc1
• Title of publication: Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage
• Authors of publication: Islam, Fahmida; Hasan, Md. Sohag; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.; Roesky, Herbert W.
• Journal of publication: RSC Advances
• Year of publication: 2023
• Journal volume: 13
• Journal issue: 5
• Pages of publication: 2841 - 2851
• a: 11.9842 ± 0.0005 Å
• b: 12.2615 ± 0.0004 Å
• c: 22.7266 ± 0.0009 Å
• α: 101.908 ± 0.002°
• β: 98.475 ± 0.002°
• γ: 94.176 ± 0.002°
• Cell volume: 3213.6 ± 0.2 ų
• Cell temperature: 193 ± 1 K
• Ambient diffraction temperature: 193 ± 1 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0482
• Residual factor for significantly intense reflections: 0.0298
• Weighted residual factors for significantly intense reflections: 0.0589
• Weighted residual factors for all reflections included in the refinement: 0.0642
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No