Information card for entry 7246161

Structure parameters

• Formula: C68 H52 O7 Os3 P2 Sb2
• Calculated formula: C68 H52 O7 Os3 P2 Sb2
• SMILES: [Os]1234([Os]([Os]([Sb]1(c1ccccc1)c1ccccc1)([Sb](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])(c1c3cccc1)[H]4)(C#[O])C#[O]
• Title of publication: Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage
• Authors of publication: Islam, Fahmida; Hasan, Md. Sohag; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.; Roesky, Herbert W.
• Journal of publication: RSC Advances
• Year of publication: 2023
• Journal volume: 13
• Journal issue: 5
• Pages of publication: 2841 - 2851
• a: 15.1736 ± 0.0004 Å
• b: 20.3459 ± 0.0006 Å
• c: 21.9689 ± 0.0006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6782.3 ± 0.3 ų
• Cell temperature: 210 ± 1 K
• Ambient diffraction temperature: 210 ± 1 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0286
• Residual factor for significantly intense reflections: 0.0265
• Weighted residual factors for significantly intense reflections: 0.0596
• Weighted residual factors for all reflections included in the refinement: 0.0603
• Goodness-of-fit parameter for all reflections included in the refinement: 1.116
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No