Information card for entry 7700197

Structure parameters

• Formula: C34 H50 Cl5 Ge Ir N2
• Calculated formula: C34 H50 Cl5 Ge Ir N2
• Title of publication: Mesityl(amidinato)tetrylenes as ligands in iridium(i) and iridium(iii) complexes: silicon versus germanium and simple κ¹-coordination versus cyclometallation.
• Authors of publication: Cabeza, Javier A.; Fernández-Colinas, José M; García-Álvarez, Pablo; González-Álvarez, Laura; Pérez-Carreño, Enrique
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 29
• Pages of publication: 10996 - 11003
• a: 11.1461 ± 0.0004 Å
• b: 12.3199 ± 0.0006 Å
• c: 15.3703 ± 0.0005 Å
• α: 82.47 ± 0.003°
• β: 79.687 ± 0.003°
• γ: 67.955 ± 0.004°
• Cell volume: 1919.99 ± 0.14 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0473
• Residual factor for significantly intense reflections: 0.0445
• Weighted residual factors for significantly intense reflections: 0.1156
• Weighted residual factors for all reflections included in the refinement: 0.1192
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No