Information card for entry 7700198

Structure parameters

• Formula: C34 H48 Cl Ge Ir N2
• Calculated formula: C34 H48 Cl Ge Ir N2
• Title of publication: Mesityl(amidinato)tetrylenes as ligands in iridium(i) and iridium(iii) complexes: silicon versus germanium and simple κ¹-coordination versus cyclometallation.
• Authors of publication: Cabeza, Javier A.; Fernández-Colinas, José M; García-Álvarez, Pablo; González-Álvarez, Laura; Pérez-Carreño, Enrique
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 29
• Pages of publication: 10996 - 11003
• a: 10.6239 ± 0.0001 Å
• b: 18.5431 ± 0.0002 Å
• c: 17.43 ± 0.0002 Å
• α: 90°
• β: 105.333 ± 0.001°
• γ: 90°
• Cell volume: 3311.49 ± 0.06 ų
• Cell temperature: 151 ± 2 K
• Ambient diffraction temperature: 151 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0284
• Residual factor for significantly intense reflections: 0.026
• Weighted residual factors for significantly intense reflections: 0.0673
• Weighted residual factors for all reflections included in the refinement: 0.069
• Goodness-of-fit parameter for all reflections included in the refinement: 1.057
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No